Tempted to pick up the Hunger Games, but the ultra violet DC turns me off of it, so I may just get that through iTunes.
Pre-ordered the Avengers, and may get it Wall-E, and the Blade Runner thing that Qwyjibo posted.
Also somewhat tempted on the Bond thing, but I don't think I can justify that, or come close to justifying it
Apocalypse Now steelbook is another distinct possibility.
Just counted and not including tv series, I have 54 blu-rays.